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幾種工業固體廢棄物固結土壤中NaCl的機理

Consolidation mechanism of NaCl in soil by various industrial solid wastes

  • 摘要: 隨著NaCl加入量的增大,利用礦渣、粉煤灰、脫硫石膏、石灰和硫酸鋁作為土壤固化劑的固結土試塊的抗壓強度先增加后減小.當NaCl的質量分數為2%左右時,固結土試塊的抗壓強度在不同的養護齡期都是最大的;而Na+和Cl-的固結率在養護時間為3~7 d增長速度很快,在養護時間為7~28 d增長速率減緩,但還是保持增長的趨勢,在養護28 d以后基本趨于穩定,基本都保持在60%~80%.通過29Si和27Al的核磁共振譜測試,發現在C—S—H網絡狀結構中大量存在四配位和六配位的鋁,而Al對Si位的取代是Na+被固化的關鍵;同時發現NaCl能夠促使Al從四配位向六配位轉化,使硅氧體系的聚合度增加.

     

    Abstract: With slag,fly ash,desulfurized gypsum,lime and aluminium sulphate as soil stabilizers,the compressive strength of consolidated soil first increased and then decreased with the amount of added NaCl increasing.The compressive strength of consolidated soil in every curing age reached its maximum value when the content of added NaCl was 2%.The consolidation rates of Na+ and Cl- increased very fast when the curing age prolonged from 3d to 7d,then slowed down from 7d to 28d,and finally kept stable in the range of 60% to 80% after 28d.The results of nuclear magnetic resonance(NMR) of 29Si and 27Al showed that there were amounts of 4-coordinated and 6-coordinated Al in the C-S-H net.The NMR analysis also indicated that in the C-S-H net some of Si4+ was substituted by Al3+.The substitution provided a condition for Na+ solidification.NaCl can promote the transformation of Al coordination from 4-coordinated one to 6-coordinated one,and improve the polymerization degree of the cementitious system.

     

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