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硝酸鈉對改善赤泥陶粒性能的影響

Effect of sodium nitrate on improvement in the properties of ceramsite using red mud

  • 摘要: 通過對赤泥化學組成、礦物組成和熱穩定性分析,進行了以赤泥中方解石本身為發泡劑及外加硝酸鈉為發泡劑制備陶粒的研究,并利用X射線衍射和掃描電鏡對所得陶粒的組成和內部結構進行了分析.結果表明:在赤泥、廢玻璃和膨潤土質量比74:15:11時,利用赤泥中的方解石可制得容重、吸水率和筒壓強度分別為1.43 g·cm-3、1.23%和22.14 MPa的陶粒.外加NaNO3發泡劑能明顯降低陶粒的容重.在赤泥、廢玻璃、膨潤土和NaNO3質量比70.0:14.2:10.2:5.6時,可制得容重、吸水率和筒壓強度分別為1.28 g·cm-3、1.54%和12.03 MPa的陶粒.陶粒中晶體礦物主要為鈣黃長石,而赤泥中主要晶體礦物為方解石.陶粒中氣孔以封閉氣孔為主,NaNO3為發泡劑時所得陶粒的氣孔率較利用赤泥自身方解石為發泡劑時高,氣孔均勻性也較好.

     

    Abstract: Based on analyzing the chemical composition,mineral composition and thermal stability of red mud,the preparation of ceramsite was investigated with calcite itself in red mud or added sodium nitrate as a foaming agent.Main components of the obtained ceramsite were analyzed by X-ray diffraction(XRD) and the internal structure was observed by scanning electron microscopy(SEM).The results show that with calcite itself as a foaming agent,the ceramsite with a bulk density of 1.43g·cm-3,a water absorption rate(WAR) of 1.23% and a cylinder compressive strength(CCS) of 22.14 MPa is prepared when the mass ratio of red mud/waste glass/bentonite is 74:15:11.However the bulk density is obviously decreased by adding sodium nitrate.The ceramsite with a bulk density of 1.28g·cm-3,a WAR of 1.54% and a CCS of 12.03 MPa is prepared when the mass ratio of red mud/waste glass/bentonite/sodium nitrate is 70.0:14.2:10.2:5.6.Crystalline phases present in the obtained ceramsite are mainly gehlenite,different from calcite in red mud based on XRD data.SEM images indicate that the majority of pores in the obtained ceramsite are sealed,and when sodium nitrate is used as a foaming agent,the porosity is higher in comparison with calcite in red mud,and the internal pore size is more uniform.

     

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