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CSP生產Ti微合金化高強鋼中納米碳化物

Nanocarbides in Ti-microalloyed high strength steel produced by CSP process

  • 摘要: 采用光學金相、電子顯微術和化學相分析的方法并結合熱力學計算,分析了緊湊式帶鋼生產(CSP)的Ti微合金化高強鋼中的析出物及其析出規律.研究發現:高強鋼中存在微米尺寸的立方TiN析出和大量納米尺寸的析出物粒子;鋼中MX相(M=Ti,Mo,Cr;X=C,N)的質量分數為0.0927%,其中10 nm以下的析出物占26.9%;均熱之前和均熱過程TiN已基本全部析出,連軋前TiC不具備析出的熱力學條件;降低鋼中N和S含量、嚴格控制卷取溫度可增加TiC的體積分數,降低γ→α相變溫度可以阻止細小碳化物長大.結果表明,析出物總的沉淀強化效果約為156 MPa,并能通過化學成分和工藝的控制進一步增強.

     

    Abstract: Optical microscopy,electron microscopy and electrolytically extracted phase analysis,in combination with thermodynamic calculations,were used to study precipitates and their precipitation behavior in Ti-microalloyed high strength steel produced by CSP process.It is found that many micron-sized cubic TiN particles and a large number of nanometer precipitates exist in the steel.The mass fraction of MX phases(M=Ti,Mo,Cr;X=C,N) in the steel is 0.0927%,in which particles smaller than 10nm account for 26.9%.Thermodynamic calculations show that titanium nitride has been almost completely precipitated from the steel during or before soaking,but titanium carbide hardly precipitates before tandem rolling.Decreasing the contents of nitrogen and sulfide and controlling the coiling temperature can increase the volume fraction of titanium carbide,and decreasing the γ→α transformation temperature can prevent fine carbides from growing.These results indicate that the precipitation hardening resulting from nanometer particles is about 156MPa and the effect can be raised through controlling the chemical composition and rolling parameters.

     

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