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Nb對轉K2彈簧鋼中MX析出相的影響

Effect of Nb on the precipitated phases of MX in switch K2 spring steel

  • 摘要: 采用Thermo-Calc熱力學軟件,對轉K2彈簧鋼在400~1600℃存在的平衡析出相及Nb、V在奧氏體相中的固溶規律進行了計算,探討了各合金元素含量對析出相析出規律的影響,并利用碳萃取復型與透射電鏡(TEM)分析了Nb含量對析出相的影響.結果表明:轉K2彈簧鋼中平衡析出相主要為MX、M7C3、M3C2和AlN;Nb能顯著提高MX相的穩定性.TEM分析表明,析出相尺寸變化范圍為幾納米到100納米以上,形態多呈近似球形或圓片狀;隨Nb含量增加,從低溫鐵素體中析出的細小顆粒所占比例顯著增大,未溶解碳氮化物比例也有所增大,總體而言析出相平均顆粒尺寸得到細化;大顆粒析出相為富Nb的碳化物,而小顆粒為富V的碳化物,這與熱力學計算結果相一致.

     

    Abstract: Equilibrium precipitated phases in switch K2 spring steel in the temperature range of 400 to 1600℃ and the solubilities of Nb and V in austenite were calculated by using the thermodynamic software Thermo-Calc to investigate the effect of alloying element content on the equilibrium precipitated phases.Then,the effect of Nb content on the precipitated phases was analyzed by carbon extraction replica and transmission electron microscopy(TEM).It is shown that the main equilibrium precipitated phases in switch K2 spring steel are MX,M7C3,M3C2 and AlN,and the stability of MX phase can be significantly improved by adding Nb.TEM results reveal that the precipitated phases are spherical or disc-shaped,and their sizes range from several nanometers to more than 100nm.With the content of Nb increasing,the proportion of fine particles which precipitated from low-temperature phase ferrite increases dramatically,and the proportion of undissolved carbonitride also increases,overall the average particles size is refined.The large precipitates are Nb-rich carbides,while the small ones are V-rich carbides,which is in accordance with the results of thermodynamic calculations.

     

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