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還原劑對高磷鮞狀赤鐵礦直接還原過程鐵還原的影響

Effects of reductants on iron reduction in the direct reduction process of high-phosphorus oolitic hematite

  • 摘要: 采用添加脫磷劑直接還原焙燒-磁選的工藝制備直接還原鐵,研究了不同還原劑對高磷鮞狀赤鐵礦直接還原過程鐵還原的影響.實驗結果和掃描電鏡分析表明,還原劑中固定碳和揮發分含量對于焙燒產物中金屬鐵晶粒的聚集、增多和長大以及所得還原鐵指標影響較大.焦炭和無煙煤所得焙燒產物中金屬鐵晶粒與脈石礦物結合較緊密,難以在磨礦過程中實現單體解離.褐煤所得焙燒產物中金屬鐵晶粒出現明顯的連接和長大,且與脈石礦物界限分明,嵌布粒度較粗,有利于鐵顆粒與脈石礦物的解離,從而其鐵回收率較其他還原劑高.

     

    Abstract: Direct reduction iron was prepared by adding dephosphorization agents during a direct reduction roasting-magnetic separation process,and the effects of reductants on the direct reduction process of high-phosphorus oolitic hematite were studied.Experimental results and SEM analysis show that the aggregation and growth of iron crystals,the increase of iron crystals' amount and the index of the reduced iron with a reductant can be influenced by the contents of fixed carbon and volatile in the reductants.When the reductant is coke or anthracite,iron crystals and gangue minerals are more closely combined in the roasting products,thus it is difficult to achieve monomeric liberation during the grinding process.When lignite is used as a reductant,the obvious connection and growth of iron crystals appear,coarser iron crystals form,and the boundary between iron crystals and gangue minerals is clear in the roasting products.Thus the liberation of iron crystals from gangue minerals is easier and the recovery of iron is higher than that obtained with other reductants.

     

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