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精煉渣成分對高強度低合金鋼中非金屬夾雜物影響

Effect of refining slag composition on non-metallic inclusions in high-strength low-alloy steel

  • 摘要: 采用渣鋼平衡的實驗方法研究了1600℃下不同堿度和不同Al2O3含量的強還原性精煉渣對高強度低合金鋼中非金屬夾雜物的影響.結果表明:渣鋼反應平衡后,爐渣中CaO和SiO2的質量比為1.9~4.5、Al2O3質量分數為21%~33%,鋼中夾雜物主要為球狀的CaO-MgO-Al2O3-SiO2系,尺寸在5μm以下,爐渣成分對夾雜物的成分影響很大.夾雜物主要分布在SiO2含量一定的CaO-MgO-Al2O3-SiO2偽三元相圖中1 400~1 500℃的低熔點區,隨著爐渣堿度的提高和Al2O3含量的降低,部分夾雜物逐漸偏離低熔點區域,夾雜物的總數量逐漸減小.當渣中Al2O3質量分數為21.22%、堿度為3.27時,有大量夾雜物分布在高熔點區域,夾雜物的總數量最小.

     

    Abstract: The effect of strongly reduced refining slag with different basicities and Al2O3 contents on non-metallic inclusions in molten steel was investigated through the slag-metal equilibrium at 1 600℃.When the slag-metal equilibrium is reached,the mass ratio of CaO to SiO2 in refining slag is from 1.9 to 4.5,and the mass fraction of Al2O3 is from 21% to 33%.Non-metallic inclusions in steel are mainly the spherical CaO-MgO-Al2O3-SiO2 system with size smaller than 5 μm.The composition of refining slag has a great effect on inclusions.Inclusions mainly distribute in the low melting point region of the CaO-MgO-Al2O3-SiO2 quasi-ternary phase diagram with stable content of SiO2 between 1 400℃ and 1 500℃.With the basicity of refining slag increasing and the Al2O3 content decreasing,part of inclusions gradually deviate from the low melting point region and the total number of inclusions decreases.When the mass fraction of Al2O3 is 21.22% and the basicity of refining slag is 3.27,lots of inclusions distribute in the high melting point region and the total number of inclusions is the smallest.

     

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