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納米SiO2粒子復合對聚脲涂層耐蝕性能的影響

Influence of nano-SiO2 particle compositing on the anti-corrosion performance of polyurea coatings

  • 摘要: 采用紫外光暴露+冷凝的紫外加速老化試驗,結合表面形貌觀察測試了納米SiO2粉體復合聚脲涂層的光老化性能,采用3.5%NaCl溶液浸泡試驗測試了涂層的耐海水浸泡腐蝕性能,通過場發射掃描電子顯微鏡、自腐蝕電位和交流阻抗圖譜等分析了不同涂層的耐蝕性能.結果表明:納米SiO2粉體顯著提高了芳香族聚脲涂層的耐蝕性能,自腐蝕電位由-40mV升高至60mV,電化學阻抗模值增加了約一個數量級,涂層進入迅速老化階段的時間延長了約120h,在3.5%NaCl溶液中的浸泡壽命提高了約600h.

     

    Abstract: The light aging performance of nano-SiO2 particle composited polyurea coatings were tested by ultraviolet accelerated aging and surface morphology observations.The corrosion resistance to seawater of the coatings was measured by soaking in a 3.5% NaCl solution.Field emission scanning electron microscopy,corrosion potential measurements and electrochemical impedance spectroscopy(EIS) were used to analyze the corrosion resistance of different coatings.The results indicate that the corrosion resistance of aromatic polyurea coatings increases significantly by compositing the nano-SiO2 powder.After the compositing,the corrosion potential improves from-40 mV to 60 mV,the EIS modulus increases approximately one magnitude,the accelerated aging stage delays about 120 h,and the life of the coatings in the 3.5% NaCl solution increases by 600 h roughly.

     

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