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鎳轉爐濺渣護爐熱態模擬

Thermal simulation of slag splashing in a nickel converter

  • 摘要: 為將濺渣護爐技術應用于煉鎳轉爐,在實驗室鎂鉻質坩堝中進行了熱態模擬濺渣實驗.結果表明:FeO-Fe2O3-SiO2-MgO渣系為鎳轉爐濺渣護爐的合理渣型,增加渣中MgO和Fe2O3含量可以明顯提高爐渣熔化溫度,相應渣中高熔點相鐵鎂橄欖石和磁鐵礦顯著增加,采用此類爐渣濺渣可在鎂鉻磚內壁形成高熔點的濺渣層;濺渣后坩堝內壁的濺渣層由反應層和掛渣層組成,其中反應層物相為鎂鐵固溶體和鎂鉻鐵鋁尖晶石,掛渣層主要由鐵鎂橄欖石和磁鐵礦組成.濺渣時采用空氣噴吹可增加渣中Fe2O3,適合作為濺渣氣源.

     

    Abstract: In order to apply the technology of slag splashing into a nickel smelting converter,the thermal simulation of slag splashing in a nickel converter was carried out with a Mg-Cr crucible in the laboratory.The results show that the FeO-Fe2O3-SiO2-MgO system is a reasonable slag type for slag splashing,increasing the contents of MgO and Fe2O3 in the slag can remarkably raise the molten temperature,and accordingly,such high melting phases as ferrohortonolite and magnetite increase dramatically.The slag splashing layer with high melting temperature can be formed by means of such a kind of slag.The inner surface of the crucible includes a reaction layer and a slag sticking layer.Phases in the reaction zone are Mg-Fe solid solution and Mg-Cr-Fe-Al spinal,while phases in the slag sticking layer are ferrohortonolite and magnetite.The Fe2O3 content can be increased by air injection,which is an ideal gas for slag splashing.

     

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