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不同溫度下60Si2MnA彈簧鋼中低熔點夾雜物生成熱力學

Thermodynamics on formation of low melting point inclusions at different temperatures in 60Si2MnA spring steel

  • 摘要: 借助FactSage熱力學軟件分別對1873、1823和1773 K三個不同溫度下60Si2MnA彈簧鋼液與MnO-SiO2-Al2O3系、CaO-Al2O3-SiO2系和CaO-Al2O3-SiO2-15%MgO系夾雜物間的平衡進行了計算.通過上述計算分析,確定了三個不同溫度下分別形成上述低熔點夾雜物時所對應的鋼液成分.經過對比還發現:低溫更有利于鋼液在低溶解氧含量條件下實現上述不同類型夾雜物的低熔點化控制.鋼液中生成低熔點SiO2-Al2O3-CaO-15%MgO系夾雜物要比生成低熔點SiO2-Al2O3-CaO系夾雜物所需的鋼液Al含量高很多,這在實際生產中更容易控制.

     

    Abstract: Equilibria between 60Si2MnA molten spring steel and such low melting point inclusions as MnO-SiO2-Al2O3 inclusions, CaO-Al2O3-SiO2 inclusions and CaO-Al2O3-SiO2-15% MgO inclusions were thermodynamically studied by the thermodynamic software FactSage at three different temperatures of 1 873, 1 823 and 1 773 K. On the basis of these calculations, the compositions of the liquid steel were determined when these low melting point inclusions formed at the different temperatures. Simultaneously, it was also discovered by comparison that low temperature is more beneficial to fulfill the control of the low melting point inclusions under the condition of low soluble oxygen content. The soluble aluminum content for the formation of CaO-Al2O3-SiO2-15% MgO inclusions is much higher than that for the formation of CaO-Al2O3-SiO2 inclusions, and it is easily controlled in actual production.

     

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