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油輪艙CO2-O2-H2S-SO2濕氣環境中低合金鋼的腐蝕行為

Corrosion behavior of low alloy steels in a CO2-O2-H2S-SO2 wet gas environment of crude oil tanks

  • 摘要: 利用自制的油輪艙CO2-O2-H2S-SO2濕氣環境腐蝕模擬裝置,對Ni和Cu含量不同的三種低合金鋼進行了油輪艙濕氣腐蝕模擬實驗,比較和分析了三種不同成分的低合金鋼在模擬原油艙濕氣環境中的腐蝕速率、腐蝕形態和腐蝕產物,探討了油輪艙CO2-O2-H2S-SO2濕氣環境中鋼的腐蝕機理.結果表明:三種不同成分低合金鋼的腐蝕形態均為全面腐蝕,伴隨著腐蝕產物的形成和脫離,鋼的腐蝕速率隨實驗時間的延長出現了波動變化;鋼中Ni和Cu元素可明顯提高鋼的耐油輪艙濕氣腐蝕性能;在油輪艙濕氣環境下,同時存在四種腐蝕性氣體CO2-O2-H2S-SO2的析氫和吸氧腐蝕,同時也存在鋼表面薄液膜中H2S被O2氧化形成的元素S引起的濕S腐蝕;CO2-O2-H2S-SO2濕氣腐蝕減薄量DLt與時間t之間較好地滿足指數關系DLt=AtB,并得到合金元素含量不同的三種鋼的系數A和指數B的數值.

     

    Abstract: Wet gas corrosion experiments of three low alloy steels containing different contents of elements Ni and Cu were conducted by homemade equipment simulating the oil tanker corrosion environment. The corrosion rate, corrosion morphologies and corrosion products of the three steels in a CO2-02-H2S-SO2 wet gas environment of crude oil tanks were compared and the corrosion mechanism was also analyzed and discussed. The results show that the corrosion morphologies of the three steels are all uniform corrosion; as the corrosion products forming and spalling, the corrosion rate of the steels fluctuates with the increase of testing time. Elements Ni and Cu can obviously improve the corrosion resistance of the steels to the wet gas environment. In the wet gas environment, hydrogen evolution corrosion and oxygen absorption corrosion caused by CO2-02-H2S-SO2 corrosion gases exist as well as wet sulfur corrosion from the oxidation of H2S by 02. The correlation between wet gas corrosion depth loss DLt and corrosion time t is properly accordant with the expo-nential relationship DLt=At8, and the values of coefficient A and exponent B of the three steels with different alloy elements were obtained.

     

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