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掃描Kelvin探針研究缺陷涂層的膜下腐蝕電化學行為

Research of electrochemical corrosion behavior under coatings with defects by scanning Kelvin probe

  • 摘要: 應用掃描Kelvin探針原位研究鹽霧和干濕周浸環境中缺陷涂層膜下的腐蝕行為.結果顯示:在兩種腐蝕環境中,缺陷涂層均分為缺陷、陰極剝離及完好涂層區域;Kelvin電位的分布相同,缺陷處最高,完整涂層處最低.Kelvin電位分布峰的直徑隨時間的延長而增大,表明剝離區域擴大.干濕周浸環境中,Kelvin電位的最大值Vmax隨時間變化不明顯,Vmin在逐漸下降后達到谷值,隨后升高;鹽霧環境中由于電解質溶液持續擴散和鹽霧顆粒極強的腐蝕性,Kelvin電位隨時間的變化規律為Vmin在起始階段達到最小值,隨后升高.由Vmax-Vmin的變化規律得出,干濕周浸環境下腐蝕傾向性在試驗開始5h后達到最大,而在鹽霧環境下,試驗開始階段腐蝕傾向性就達到最大,且要高于干濕周浸環境.

     

    Abstract: The corrosion behavior under coatings with a point defect was investigated in situ by means of scanning Kelvin probe in both salt spray test and cyclic wet-dry immersion test.The results showed that the Kelvin potential distribution was identical in both the tests due to the same division of coating surfaces:defect area with the highest potential,delaminated area,and intact area with the lowest potential.Through monitoring the augment of diameter of Kelvin potential peaks with time,the expansion of the delaminated area was revealed.In cyclic wet-dry immersion test,the highest Kelvin potential Vmax did not change obviously with time while the lowest potential Vmin increased after reaching at the valley.On the other hand,in salt spray test,different from the rule in cyclic wet-dry test,Vmin was minimized at the first stage of the test resulted from the continued diffusion of the electrolyte and the corrosive ability of slat spray particles.Based on the changing pattern of Vmax-Vmin,it was concluded that in cyclic wet-dry immersion test,the tendentiousness of corrosion got the highest level when the test kept going for 5 h.However,in salt spray test,it achieved the highest level just at the beginning of the test and was more intensive than that in cyclic wet-dry immersion test.

     

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