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含鋁TRIP鋼結晶器保護渣黏度特性

Viscosity characteristic of mold fluxes for TRIP steel containing Al

  • 摘要: 含鋁TRIP鋼鋼液中Al易與結晶器保護渣中的SiO2發生氧化-還原反應,使其保護渣中Al2O3的質量分數由3%快速增加到30%左右,w(Al2O3)/w(SiO2)由0.10增加到1.44,導致黏度發生大的波動.研究了Al2O3含量和w(Al2O3)/w(SiO2)對含鋁TRIP鋼保護渣黏度的影響,建立了高Al2O3含量保護渣系黏度的計算模型.結果表明:隨著Al2O3質量分數由3%增加到17%,綜合堿度R<1的保護渣黏度先增大再減小,而R≥1的保護渣黏度變化較小;隨著Al2O3質量分數由17%增加到30%,保護渣的黏度快速增大;隨著w(Al2O3)/w(SiO2)的增大,Al-TRIP鋼保護渣的黏度呈現先快速減小而后迅速增大的趨勢.

     

    Abstract: The oxidation-reduction reaction can easily happen between Al contained in liquid steel and SiO2 component in mold fluxes during continuous casting of TRIP steel containing Al.As a result,the Al2O3 component sharply increases from 3% to 30%,and the w(Al2O3)/w(SiO2) ratio simultaneously ascends from 0.10 to 1.44,so the viscosity could have a bigger fluctuation accordingly.The effects of Al2O3 content and w(Al2O3)/w(SiO2) ratio on the viscosity of mold slags were investigated for producing TRIP steel containing Al.A model was built to predict the viscosity of the high Al2O3 slag system.The results indicate that when the comprehensive basicity is less than 1,the viscosity of mold fluxes initially rises and then reduces again with increasing the Al2O3 content from 3% to 17%,but it changes slightly when the basicity is greater than 1.The viscosity of mold fluxes dramatically rises when the Al2O3 content changes from 17% to 30%.With increasing w(Al2O3)/w(SiO2) ratio,the viscosity of mold fluxes for TRIP steel containing Al initially reduces and then abruptly rises.

     

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