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紅土鎳礦直接還原焙燒磁選回收鐵鎳

Recovery of iron and nickel from nickel laterite ore by direct reduction roasting and magnetic separation

  • 摘要: 采用添加助熔劑直接還原焙燒-磁選方法,對鎳主要以硅酸鎳形式存在的低品位紅土鎳礦中鎳和鐵的富集進行了研究.結果表明,同時添加助熔劑,可獲得較好的技術指標.最佳工藝條件為:煤作還原劑,質量分數為15%;KD-2為助熔劑,質量分數為20%;焙燒溫度為1200℃;焙燒時間為40min.在此條件下可以得到鎳品位10.83%、鐵品位52.87%、鎳回收率82.15%和鐵回收率54.59%的鎳鐵精礦.用X射線衍射(XRD)和透射電鏡(TEM)對還原過程中助熔劑和煤的作用機理進行了研究.發現KD-2可以與原礦中含鎳的石英和硅酸鹽礦物反應,釋放出其中的鎳;煤用量太多時可生成部分不含鎳的金屬鐵,會造成鎳的回收率降低.

     

    Abstract: By adding a flux and using a direct reduction roasting and magnetic separation method,iron and nickel enrichment from refractory low-grade nickel laterite ore,in which nickel is mainly contained in silicates,was studied.Better technical indicators were obtained by adding the flux.The optimal conditions are coal as the reducer with a dosage of 15%,KD-2 as the flux with a dosage of 20%,and roasting at 1200℃ for 40min.A concentrate of the Ni content of 10.83% and the Fe content of 52.87%,with the Ni recovery of 82.15% and the Fe recovery of 54.59%,was produced under the optimal conditions.The action mechanisms of KD-2 and coal were also investigated by XRD and TEM.The results show that KD-2 can react with quartz and silicates containing Ni,leading to releasing Ni from the quartz and silicates.An overdosage of coal in the reduction roasting process can result in the formation of pure iron,in company with a decrease in nickel recovery.

     

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