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金屬間化合物的比熱容估算模型

Estimating model of specific heat of intermetallics

  • 摘要: 在分析已有的熱力學數據基礎上,建立了估算二元金屬間化合物比熱容的雙參數模型.用此模型可以估算由簡單金屬形成的二元金屬間化合物的比熱容,涉及Fe、Si、Nb、Ti、Cu、Co和Mg等多個體系.估算了132個已知金屬間化合物AlCa、AlCo、CrNi、FeTi、FeSi、FeNb和MoSi等的比熱容,平均誤差為2.74J·mol-1·K-1,標準差為3.84J·mol-1·K-1.用雙參數模型估算的比熱容精度高,其估算誤差小于離子束縛模型.

     

    Abstract: Based on an analysis of existing thermodynamic data, a two-parameter model for estimating the specific heat of a dual intermetallic is developed. It can estimate the specific heats of dual intermetallics composed of simple metals involving Fe, Si, Nb, Ti, Cu, Co, Mg, etc. The specific heats of 132 intermetallics are estimated, such as AlCa, AlCo, CrNi, FeTi, FeSi, FeNb, and MoSi. It is found that the average error of specific heat is about 2.74J·mol-1·K-1 and the standard deviation is 3.84J·mol-1·K-1. The precision of standard entropy estimated by the two-parameter model is higher than that estimated by the ion binding model.

     

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