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高級別管線鋼鈣處理效果評價標準

Evaluation standard of calcium treatment in high grade pipeline steel

  • 摘要: 對X70管線鋼進行了六爐鈣處理實驗.結果表明:鈣處理后管線鋼生產的后續工序中鋼中鈣含量顯著下降,夾雜物組成和形貌發生顯著變化;二次氧化會降低管線鋼鈣處理效果,但鋼中溶解鈣和較高CaO含量的CaO-Al2O3復合夾雜可對鋼水二次氧化產生的Al2O3發生改性作用;高級別管線鋼鈣處理效果與鋼中鈣含量、氧含量、硫含量、鋼水二次氧化程度以及鈣處理后續時間等有關,采用鋼中Ca含量、%CaTot/%Als、%CaTot/TO、ACR和%CaTot/%S作為鈣處理效果的評判標準均存在缺陷.本文建議鈣處理效果評判標準為:①鑄坯中心部位或軋后板帶中心部位不存在單純的MnS夾雜;②中間包和結晶器中夾雜的nCaO/Al2O3應該與12CaO·7Al2O3相近;③鈣處理后夾雜的nCaO/Al2O3應稍高于12CaO·7Al2O3的夾雜.同時還必須注意鈣處理應在最后精煉工序的后期進行,盡量防止鋼水的二次氧化.

     

    Abstract: Calcium treatment experiments were carried out on six heats of X70 pipeline steel.The results show that the Ca content of the steel dropped a lot and the composition and morphology of inclusions varied obviously in producing the steel after calcium treatment.Reoxidation deteriorates the effect of calcium treatment,but dissolved calcium and CaO-Al2O3 compound inclusions with high CaO content can play a role of modification on Al2O3 caused by reoxidation.The calcium treatment effect of high grade pipeline steel is related with the concentrations of calcium,oxygen and sulphur,reoxidation degree,and time after treatment,but evaluating calcium treatment with calcium content,%CaTot/%Als,%CaTot/TO,ACR and %CaTot/%S is improper.A evaluation standard is put forward as the following:(1) pure MnS inclusions do not exist in the central area of slabs or rolled plates,(2) nCaO/Al2O3 of inclusions in the tundish and mould is controlled around that of 12CaO·7Al2O3,and (3) nCaO/Al2O3 of inclusions after calcium treatment is higher than that of 12CaO·7Al2O3.It is also be careful that calcium treatment is carried out at the end of the final refining procedure so as to prevent reoxidation of liquid steel.

     

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