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氯化鑭對2024鋁合金縫隙腐蝕的緩蝕作用

Inhibition of lanthanum chloride on the crevice corrosion of 2024 aluminum alloy in seawater

  • 摘要: 為了降低2024鋁合金在海水中的縫隙腐蝕敏感性,采用浸泡和動電位極化、電化學阻抗等研究了氯化鑭(LaCl3)對該鋁合金縫隙腐蝕行為的影響,并通過原子力顯微鏡對縫隙試樣內、外腐蝕產物膜的形貌進行了觀察.結果表明:當海水中LaCl3的質量濃度超過2.0 g·L-1以后,它能有效地減緩2024鋁合金在海水中的縫隙腐蝕.這主要是因為LaCl3減緩了縫隙的陰極反應速率,降低了縫隙內、外的氧濃度差,且縫隙內、外生成的均勻致密的腐蝕產物膜降低了Cl-侵蝕性,這些因素抑制了縫隙的萌生與擴展,提高了2024鋁合金在海水中的抗縫隙腐蝕能力.

     

    Abstract: To reduce the susceptibility of crevice corrosion of 2024 aluminum alloy in seawater,the effect of LaCl3 on the crevice corrosion behaviour of the alloy was investigated by immersion,potentiodynamic polarization and electrochemical impedance spectroscopy.The micrographs of corrosion product films formed on the inside and outside of crevice samples were observed by atomic force microscopy.The results show that when the concentration of LaCl3 in seawater is in excess of 2.0 g·L-1,the crevice corrosion may be inhibited obviously.It is because that the cathodic reaction rate of crevices is decreased and the oxygen concentration difference between the inside and outside of crevices is reduced.Moreover,the uniform corrosion product film formed on the inside and outside of crevices blocks the aggressiveness of Cl-.The initiation and propagation of crevice corrosion are restrained by these factors,and thus the crevice corrosion resistance of 2024 aluminium alloy in seawater is improved.

     

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