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20CrMnTi滲碳齒輪鋼中Ti(C,N)的粗化行為

Ostwald ripening of Ti(C,N) in 20CrMnTi gear steels

  • 摘要: 基于第二相Ostwald熟化的相關理論,對5爐成分有細微差別的20CrMnTi滲碳齒輪鋼中Ti(C,N)在930℃下的粗化規律進行了計算.結果表明,在930℃滲碳溫度下分別保溫1、2、4、8、16h,隨著保溫時間的延長,各爐鋼中碳氮化鈦顆粒均會發生一定程度的粗化,第二相的粗化速率系數m值越大,粗化行為越嚴重.在保溫8h時,t時間后第二相的平均尺寸dt變化范圍為2.64~16.2nm,最大偏差在13nm左右;保溫16h時,dt變化范圍為3.33~20.4nm,最大偏差約為17nm,表明Ostwald熟化作用對Ti(C,N)第二相顆粒尺寸的影響不大.對釘扎奧氏體晶界、阻止奧氏體晶粒長大起主要影響作用的是第二相顆粒的初始尺寸.

     

    Abstract: Based on the theories of Ostwald ripening, the coarsening law of Ti(C, N) in 20CrMnTi gear steel was calculated at 930℃. The results show that when the holding time is 1, 2, 4, 8, 16 h, with the increase of holding time, the coarsening of Ti(C, N) particles would occur to some extent. While the coarsening rate coefficients m of second phase is greater, the coarsening is more serious. The range of dt which is the average size of the second phase at t time is 2.64-16.2 nm and 3.33-20.4 nm when the holding time is 8 h and 16 h respectively with the maximum deviation 13 nm and 17 nm apart. So Ostwald ripening has little effect on the particle size of second phase Ti(C, N), and it is the original size of the particles that has the main influence on pinning the grain boundaries and preventing austenite grain growth.

     

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