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含氮316L不銹鋼氮合金化工藝研究

Study on the nitrogen alloying process of nitrogen-contained 316 L stainless steel

  • 摘要: 在常壓和真空條件下研究了溫度與氮分壓對316L不銹鋼中氮溶解度的影響,鋼中氮的溶解度隨著溫度的降低而升高,隨著氮分壓的增大而增大.建立了316L不銹鋼氮溶解度熱力學計算模型,不同吹氮條件下氮溶解度實測值與熱力學模型計算值較吻合.在1773~1873K條件下,生產控氮型316L不銹鋼,氮分壓要控制在6~28kPa以上;生產中氮型316L不銹鋼,氮分壓要控制在22~101kPa以上.常壓下吹氮10min,鋼液含氮量即可超過0.10%.

     

    Abstract: The influences of liquid steel temperature and nitrogen partial pressure on the nitrogen solubility in 316 L stainless steel under normal atmosphere and vacuum were studied. The nitrogen solubility increased with decreasing the liquid steel temperature or increasing the nitrogen partial pressure. A thermodynamic model was developed to calculate the nitrogen solubility in 316 L stainless steel, and the calculated results were in coincidence with the measurement results under different nitrogen blowing processes. At 1 773 to 1 873 K, the nitrogen partial pressure must be over 6-28 kPa to produce 316LN (N:0.05%-0.10%, mass fraction, so as the follows), and must be over 22-101 kPa to produce 316 LN (N:0.10%-0.40%). The nitrogen content was over 0.01% in the condition of nitrogen blowing for 10 min under normal atmosphere.

     

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