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超聲-浸漬法制備介孔MnO2及其性質表征

Ultrasonic dipping synthesis and characterization of mesoporous MnO2

  • 摘要: 采用超聲-浸漬法,以SBA-15為硬模板、Mn(NO3)2為錳源制備出介孔MnO2.采用X射線衍射(XRD)、掃描電鏡(SEM)、氮氣吸附-脫附以及熱重-差熱方法(TG/DTA)對樣品的物理結構進行表征;用恒流充放電、循環伏安和電化學阻抗(EIS)考察樣品作為超級電容器電極材料的性能.結果表明,樣品MnO2復制了SBA-15的介孔結構,比表面積、平均孔徑分別為282m2·g-1和2.75nm;介孔MnO2作為超級電容器電極材料,具有良好的動力學可逆性,電荷轉移電阻小,電化學活性較高,首次放電比容量為285 F·g-1,循環500次后仍保持在210 F·g-1.

     

    Abstract: A ultrasonic dipping method was used to prepared mesoporous MnO2 with SBA-15 as a hard template and Mn(NO3)2 as a Mn source. The texture/structures of the samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), nitrogen adsorption-desorption and thermogravimetry-differential thermal analysis (TG/DTA). Galvanostatie charge-discharge, cyclic voltammetry and electrochemical impedance spectroscopy (EIS) were performed to investigate the electrochemical performanee of the samples. The results indicated that the synthesized MnO2 fabricated SBA-15 structure. The specific surface and mesopore size of the synthesized MnO2 were 282 m2·g-1 and 2.75 nm, respectively. As an electrode material of supercapaeitors, mesoporous MnO2 exhibited favorable reversible kinetic characteristics, low charge transfer resistance and high electrochemical activity, which had a initial specific capacitance of 285 F·g-1 and retained at 210 F·g-1 after 500 cycles.

     

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