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礬土基Al2O3-MgO質振動澆注料的流變性能

Rheological property of bauxite based Al2O3-MgO vibration castable

  • 摘要: 采用新型澆注料全組分流變儀,針對礬土基Al2O3-MgO質振動澆注料,測定了不同種類硅灰及其加入量、鎂砂粉加入量、三聚磷酸鈉加入量和不同粒度分布系數對流變性能的影響.研究結果表明:在振動條件下,全組分鋁鎂質振動澆注料具有Bingham流體的特征,并具有剪切稀化和正觸變性.硅灰種類對澆注料的流變性有一定的影響.硅灰含量(質量分數3%~5%)對澆注料的流變性有較大影響,隨著硅灰加入量的增大,澆注料的流變性逐漸變好.在實驗的鎂砂粉粒度下,鎂砂粉含量(質量分數4%~12%)對澆注料的流變性影響較小.三聚磷酸鈉加入量(質量分數0.13%~0.19%)對澆注料的流變性影響較大,隨分散劑加入量的增加澆注料的流變性逐漸變好,在0.19%時又變差,最佳加入量為0.15%~0.17%.隨粒度分布系數增大(0.23~0.31),澆注料所需的加水量逐漸降低,流變性逐漸變好,0.29以后變化不大.澆注料的流變性和流動性有較好的相關性.澆注料的流變性越好,流動性也越好.

     

    Abstract: The effect of the kind and content of silica fume, the contents of magnesia fine and sodium tripolyphosphate (STP), and particle size distribution coefficient (Andreasen coefficient) on the theological property of bauxite-based Al2O3-MgO castable were researched with a new developed castable rheometer. The results show that under vibration conditions, the castable has characteristics of the Bingham model, with shear-thinning and thixotropic property. The type of silica fume has some effect on the rheology of the castable. The content of silica fume in the range of 3% to 5% has significant effect on the theology of the castable; with the increase of silica fume's addition, the rheology of the castable gets better. At the particle size of magnesia fine in this experiment, the content of magnesia fine in the range of 4% to 12% has little effect on the rheology of the castable. The addition of STP in the range of 0.13% to 0.19% has obvious effect on the rheology of the castable. With the increase of STP's addition, the rheology of the castable get better, but the effect gets worse at the addition of 0.19%. The best addition of STP is 0.15% to 0.17%. With the increase of particle size distribution coefficient in the range of 0.23 to 0.31, the water demand for the same flow value is decreased, and the rheology get better too, but no more effect when higher than 0.29. There is good relevance between the rheology and flow ability. The better the rheology, the better the flow ability is.

     

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