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D32海洋平臺用鋼在浪濺區腐蝕行為

Corrosion behavior of D32 steel for offshore platforms at the splash zone

  • 摘要: 通過極化實驗和阻抗實驗研究了D32海洋平臺用鋼在浪濺區的腐蝕規律,并利用掃描電鏡和能量色散譜儀分析了各鋼樣的腐蝕產物.結果表明,腐蝕產物的形貌成分和覆蓋度的不同導致了模擬全浸區腐蝕速率稍大于鋼樣在海水中的腐蝕速率,模擬浪濺區腐蝕速率遠大于模擬全浸區鋼樣腐蝕速率.鋼樣在青島海水、埕島海水的全浸區和浪濺區的Nyquist圖中出現的韋伯阻抗是由于表面形成的銹層及鈣鎂層所致.

     

    Abstract: The corrosion behavior of D32 steel for offshore platforms was studied at the splash zone with polarization curves and electric impedance spectroscopy (EIS). Scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were employed to analyze the corrosion rusts. Because of different microstructures, components and cover degrees of the corrosion rusts, the samples at the immersion zone corroded a little more seriously than those at the seawater, whereas the samples at the splash zone corroded much more seriously than those at the immersion zone. It was due to the rust layer and calcium magnesium layer formed on the surface of the steel that the Warburg impedance appeared in the Nyquist figure at the immersion zone and splash zone of Qingdao and Chengdao seawater.

     

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