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Cu、As和Sn對低合金鋼連鑄坯第Ⅲ脆性區的影響

Effect of Cu,As and Sn on the low ductility region Ⅲ of low alloy steel continuous casting slabs

  • 摘要: 為了研究殘余元素Cu、As和Sn對鋼高溫延塑性的影響,采用Gleeble-1500熱模擬試驗機測試了含有一定量Cu、As和Sn低合金鋼連鑄坯的高溫延塑性,得到了低合金鋼第Ⅲ脆性溫度區在920~730℃之間.結果表明:第Ⅲ脆性溫度區脆化的主要原因是奧氏體單相區低溫域鋼中Cu、As和Sn等殘余元素在奧氏體晶界的偏聚削弱晶界結合能,導致試樣沿晶脆性斷裂;奧氏體和鐵素體兩相區在原奧氏體晶界析出的網狀鐵素體導致試樣沿晶開裂.鋼中的Cu、As和Sn元素增加第Ⅲ脆性溫度區的寬度和脆性凹槽的深度,同時提高第Ⅲ脆性溫度區的上限臨界溫度.

     

    Abstract: To investigate the effect of residual elements Cu, As and Sn on the hot ductility of steels, the hot ductility of low alloy steel continuous casting slabs containing some Cu, As and Sn was measured by tensile tests with a Gleeble-1500 tensile test machine. It is found that the low ductility region Ⅲ is between 920 and 730℃. Embrittlement in the region Ⅲ is caused by Cu, As and Sn segregation along the austenite intergranular in the austenite single-phase low-temperature range, which weakens the binding energy of the intergranular and induces brittle fracture along the intergranular; the precipitation of proeutectoid ferrite film along the austenite intergranular in the austenite and ferrite two-phases range induces intergranular cracks. Cu, As and Sn in the steel increase the width and depth of the low ductility region In and enhance its upper limit critical temperature.

     

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