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低碳貝氏體鋼在三種典型環境中的腐蝕行為和腐蝕產物

Corrosion behavior and corrosion products of a low carbon bainite steel in three kinds of typical environments

  • 摘要: 通過干濕循環加速腐蝕實驗并結合X射線衍射、掃描電鏡、能譜分析和N2吸附等方法,研究了低碳貝氏體鋼在用相應溶液模擬的三種大氣環境(海洋、工業和海洋工業大氣)中加速腐蝕行為和腐蝕產物特征.實驗結果表明,低碳貝氏體鋼在三種環境中的腐蝕速率均低于商業化耐候鋼09CuPCrNi.低碳貝氏體鋼在上述三種環境中的腐蝕速率也有較大差別,其在含有復合腐蝕因子(Cl-和SO32-)的環境中腐蝕最為嚴重,而在只含腐蝕因子SO32-的環境中腐蝕程度最輕.在不同環境中形成的腐蝕產物相組成差別很小,但銹層致密程度相差較大,并且銹層越致密,對應的鋼腐蝕速率越低.在三種環境中的腐蝕對鋼的拉伸力學性能的影響較小,說明沒有產生嚴重的局部腐蝕.

     

    Abstract: Wet-dry cyclic accelerated corrosion tests together with XRD, SEM, EDS and N2 adsorption technology were employed to investigate the corrosion behavior and corrosion products of a low carbon hainite steel. The steel was subjected to three kinds of atmospheric environments, i.e. marine environment, industrial environment and marine industrial environment, which were simulated by corresponding solutions. It is found that the corrosion rates of the low carbon bainite steel are lower than that of the commercial weathering steel 09CuPCrNi in all the three kinds of environments. The corrosion rates of the hainite steel in the three kinds of environments are also different. In the environment containing both Cl- and SO32- the corrosion is the most serious, while in the environment only containing SO32- the corrosion is the lightest. The distinction of corrosion products in the three kinds of environments is neglectable, while the compact degree of rust layers formed in different environments is obviously different. The more compact the rust layer is, the lower corrosion rate the steel exhibits. There is no serious selective corrosion in the bainite steel for the corrosion has little effect on its tensile mechanical properties.

     

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