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溫度對Q235鋼在大港土中腐蝕行為和機理的影響

Influence of temperature on the corrosion behavior and mechanism of Q235 steel in Dagang soil

  • 摘要: 利用極化曲線、線性極化和電化學阻抗譜(EIS)研究了Q235鋼在20~70℃、含水20%的大港土中的腐蝕行為.實驗表明:Q235鋼的腐蝕電流密度隨溫度升高而增大,線性極化電阻Rp及電荷轉移電阻Rt隨溫度升高而減小;在陽極極化100~200 mV區間,Q235鋼的電極過程受到了一定阻滯,E~lgI曲線在該極化區間內的斜率隨溫度升高而呈指數衰減;利用腐蝕電流密度和線性極化電阻所計算的Stern公式中的B值要大于活性區均勻腐蝕所對應的B值,在實驗溫度范圍內,其數值基本維持在44.2 mV左右;線性極化電阻Rp是整個電極反應過程的綜合體現,在含水20%的大港土中,由于受擴散過程控制,Rp的數值要比電荷轉移電阻Rt大得多.

     

    Abstract: The corrosion behavior of Q235 steel in Dagang soil with a 20% water content at different temperatures was studied by the means of polarization curve, linear polarization and electrochemical impedance spectroscopy (EIS). The results indicate that at the range of 20 to 70℃, with increasing temperature the corrosion current density Icorr increases, and the linear polarization resistance Rp and the charge transfer resistance Rt depress. At the range of 100 to 200 mV of anodic polarization, the electrode reaction of Q235 steel is blocked, and the slops of E to lgI curves exponentially decrease with increasing temperature. The value of B which is calculated by the corrosion current density Icorr and the linear polarization resistance Rp is bigger than the one which accounts for active uniformity corrosion, and keeps constant at about 44.2 mV. Due to the control of diffusion process, the linear polarization resistances Rp is much bigger than the charge transfer resistance R t obtained from equivalent circuit simulation of EIS technology.

     

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