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三元乙丙橡膠的人工氣候老化

Artificial weathering of ethylene-propylene-diene monomer (EPDM) rubber

  • 摘要: 利用氙燈人工氣候箱對三元乙丙橡膠(EPDM)進行人工氣候老化實驗,采用X射線光電子能譜(XPS)、掃描電子顯微鏡(SEM)、電子萬能試驗機和色度計研究了人工氣候老化對EPDM化學結構、表面形貌、力學性能和顏色的影響.結果表明:在氙燈人工氣候環境中老化90d后,EPDM表面生成一層厚度約2μm的氧化膜,其組成包括有C-O-C/C-OH、C=O和O-C=O;交聯密度隨老化時間的變化基本呈線性增加;隨老化時間的延長,試樣表面粗糙度增加,有孔洞和微裂紋生成,拉伸強度、撕裂強度和硬度增加,EPDM試樣表面變紅變黃,亮度增加.

     

    Abstract: The effects of artificial weathering on the chemical structure, surface topography and mechanical properties of ethylenepropylene-diene monomer (EPDM) were investigated by X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), computer-controlled testing machine and spectrophotometer. The results showed that an oxidation layer formed after 90 d of exposure. XPS results confirmed the production of C-O-C/C-OH, C=O and O-C=O groups. With prolonging exposure time, the crosslink density increased linearly, the surface of EPDM turned to redder, more yellow and lighter. Little voids and micro cracks were formed under exposure to artificial weathering environment. The tensile strength, tear strength and hardness increased with prolonging exposure time.

     

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