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薄膜厚度對1-3型BaTiO3-CoFe2O4多重鐵性薄膜相變溫度的影響

Effect of thickness on the critical phase transition temperature of 1-3 type BaTiO3-CoFe2O4 multiferroic composite thin films

  • 摘要: 基于熱動力學理論,通過對演化方程的線性穩定分析,確定了1-3型BaTiO3-CoFe2O4(BTO-CFO)多重鐵性復合材料中的鐵電、鐵磁相變溫度.考慮系統中基底與薄膜之間及薄膜內鐵電相、鐵磁相之間的內應力和外應力的彈性耦合,確立了順電到鐵電/鐵磁地相變臨界溫度地解析式.臨界溫度與兩相體積分數、基底、薄膜的晶格尺寸、薄膜兩相的材料性能及薄膜厚度都有很大關系.兩相的相變臨界溫度可以通過調節體積分數及薄膜厚度進行控制.

     

    Abstract: Based on the thermodynamic theory, the critical phase transition temperature of 1-3 type multiferroic composite BaTiO3-CoFe2O4 was investigated by linear stability analysis, Taking into account the coupled elastic stress on the interfaces of ferroelectric/ferromagnetic phases and film/substrate, the analytic expressions of para-ferro transition temperature of the epitaxial multiferroic composite thin film were derived as a function of volume fraction, lattices parameters, material constants and thin film thickness, The results show that the critical phase transition temperature can be controlled by adjusting the volume fraction or thickness of the composite thin film.

     

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