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工藝參數對凝膠注模成型不銹鋼坯體強度和燒結密度的影響

Effects of process parameters on the gelcasting green strength and sintered density of stainless steel

  • 摘要: 為了制備高坯體強度和燒結密度的凝膠注模成型不銹鋼制件,研究了凝膠注模工藝參數包括預混液單體含量和單體/交聯劑比例、漿料固相含量及引發劑加入量等對坯體抗彎強度及燒結體密度的影響規律.結果表明,對于316L不銹鋼的凝膠注模成型,可同時獲得較好的坯體強度和燒結密度的工藝條件為:預混液單體質量分數18%~22%,單體/交聯劑比例90∶1~240∶1;漿料固相體積分數52%~55%;引發劑用量約為單體質量的0.8%~1.4%.最終獲得坯體強度高于30.0MPa、燒結密度高于97%的復雜形狀燒結不銹鋼零件,其燒結體力學性能略低于粉末注射成型時的性能,但遠高于美國MPIF標準.

     

    Abstract: An approach for fabricating sintered stainless steel with high green strength and sintered density by gelcasting was presented. The effects of gelcasting process parameters such as monomer content, ratio of monomer/cross-linker in premixed solution, solid loading of slurry, and initiator content on the green strength and sintered density of stainless steel were investigated. The results show that the appropriate process parameters of 316L stainless steel gelcasting are as follows, monomer mass fraction 18%-22%, ratio of monomer/cross-linker 90:1-240:1, solid loading 52%-55%, and initiator content 0.8%-1.4% (based on the mass of monomer). Under the above condition, complex-shaped stainless steel parts with green strength more than 30.0 MPa, sintered density more than 97% and mechanical properties slightly less than those of parts by metal powder injection molding (MIM) were obtained.

     

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