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水分及溫度對煤吸附甲烷的影響

Effect of moisture and temperature to CH4 adsorption of coal

  • 摘要: 采用煤吸附甲烷參數測定裝置,研究了水分及溫度對煤吸附甲烷的影響,對完善間接法測定煤層瓦斯含量具有重要意義.對不同變質系列的4種煤樣,進行了干燥和不同水分條件下的等溫吸附實驗.結果表明Langmuir吸附模型擬合精度最高,并得到水分對吸附影響的校正公式.不同溫度下的等溫吸附實驗表明,隨著溫度的升高,煤吸附甲烷量減小,但變化趨勢并不明顯.研究得到了實驗測定甲烷含量的校正公式及其相對誤差.

     

    Abstract: Adopting the parameters measure equipment for CH4 adsorption of coal,the effects of moisture and temperature to CH4 adsorption of coal were studied.The results have important meaning to perfecting indirect methods for measuring the gas quantity absorbed in coal.Using four coal samples at different metamorphic stages,isothermal adsorption experiments at dryness and different moistures were carried out.The fit precision of Langmuir adsorption model is best.The emendation equation for moisture effects on adsorption was gained.The results of isothermal adsorption experiment at different temperatures showed that the adsorptive capacity of coal decreases with increasing temperature,but the change is not obvious.The emendation equation and its relative error for measuring the gas quantity of coal at laboratory were gained.

     

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