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激光區熔定向凝固Al2O3/YAG/ZrO2共晶自生復合陶瓷的顯微組織與斷裂韌性

Microstructure and fracture toughness of directionally solidified Al2O3/YAG/ZrO2 eutectic ceramics by laser zone remelting

  • 摘要: 采用激光區熔定向凝固技術制備Al2O3/YAG/ZrO2共晶自生復合陶瓷,研究其在超高溫度梯度、不同激光工藝條件下的快速凝固組織特征及其相互影響,并對其力學性能以及增韌機制進行了分析.研究結果表明:(1)激光區熔定向凝固Al2O3/YAG/ZrO2共晶由α-Al2O3、YAG以及ZrO2三相組成,不存在其他相以及相間晶團.各相均勻連續分布,耦合生長,呈網狀結構,是典型的快速凝固層片狀非規則共晶組織.(2)在一定的激光功率密度下,共晶間距隨掃描速度的增大急劇減小,最小間距僅為0.2~0.3μm.(3)Y2O3在ZrO2中具有一定的固溶度,固溶程度不同時,ZrO2呈現不同的形貌.(4)定向凝固Al2O3/YAG/ZrO2共晶陶瓷的硬度高達18.67GPa,室溫斷裂韌性為8.0MPa·m1/2.第三組元ZrO2的加入、相的小尺寸效應以及裂紋分叉是韌性增強的主要原因.

     

    Abstract: Directionally solidified Al2O3/YAG/ZrO2 eutectic ceramics were prepared by laser zone remelting technique to investigate the rapid solidification microstructure characteristic under ultra-high temperature gradient and different laser processing conditions. The fracture toughness and toughen mechanism were analyzed and discussed. The results show the following. (1) The directionally solidified Al2O3/YAG/ZrO2 eutectic ceramic shows a ‘Chinese script’ microstructure consisting of only three phases of Al2O3, YAG and ZrO2, and no other phases and colonies. The three phases distribute homogeneously and continuously, connect and finely couple each other to form an interpenetrating network, which belongs to the typical lamellar structure of a rapidly solidified irregular eutectic. (2) The eutectic spacing decreases with the increase of scanning rate under certain laser power intensity, and the smallest spacing is only about 0.2~0.3 μm. (3) Some amount of Y2O3 dissolves in ZrO2 phase and this influences the micro-patterns of ZrO2. (4) The maximum hardness reaches 18.67 GPa and the room-temperature fracture toughness is 8.O MPa·m1/2. Adding the third component of ZrO2, small size of phases and crack branching may contribute to the increased fracture toughness.

     

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