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高性能堿土耐熱鎂合金的顯微組織和蠕變性能

Microstructures and creep properties of high-performance heat-resistant magnesium-alkaline earth alloys

  • 摘要: 利用光學顯微鏡(OM),掃描電鏡(SEM)及透射電鏡(TEM)系統研究了堿土元素Sr和Ca加入Mg-4Al基合金后的顯微組織,并測試了其抗蠕變性能.實驗合金的鑄態組織均由α-Mg和沿枝晶界分布的第二相組成.2%Sr加入基體合金中能觀察到沿晶界的離異共晶和層片共晶Al4Sr相及塊狀三元τ相.2%Ca的加入則形成了晶界層片Mg2Ca共晶和晶內的Al2Ca顆粒.而在Mg-4Al-2Sr-1Ca中,晶界相為塊狀τ相和層片狀Mg2Ca共晶,晶內也析出Al2Ca顆粒.在Mg-4Al-2Sr-1Ca基礎上提高Al含量,粗大不規則共晶(Mg,Al)2Ca相在晶界處形成并不斷增多,Mg2Ca及τ相逐漸減少,當Al含量到7%時,出現了新的細小層片狀Al4Sr相.Sr、Ca元素加入Mg-Al合金,改善了合金的抗蠕變性能,其中Mg-5Al-2Sr-1Ca和Mg-6Al-2Sr-1Ca合金顯示所有實驗合金中最好的蠕變抗力.根據Power-law公式,在175℃/50~80MPa和70MPa/150~200℃蠕變下,Mg-4Al-2Sr合金在較低應力(<60MPa)下蠕變表現為擴散控制的位錯攀移機制,而在高應力下出現Power-law公式的失效;Mg-4Al-2Sr-1Ca合金蠕變則受到了擴散控制的位錯機制和晶界滑移機制的共同作用.

     

    Abstract: The microstructures of Mg-4Al alloys containing alkaline earth Sr and Ca were investigated by optical microscope (OM), scanning electronic microscope (SEM) and transmission electron microscope (TEM), and creep properties were also tested. The as-cast microstructure of the studied alloys consists of dendritic a-Mg and grain boundary second-phases. Divorced eutectic and lamellar eutectic Al4Sr, and bulky ternary τ phase are observed along grain boundary with 2% of Sr addition to the based alloy. 2% of Ca addition results in the formation of lamellar eutectic Mg2Ca at grain boundary and Al2Ca particles in grains. In the Mg-4Al-2Sr-ICa alloy, grain boundary phases are r phase and lamellar eutectic Mg2Ca, and Al2Ca particles are also precipitated in grains. With the increase of Al content in the Mg-4Al-2Sr-ICa, the coarse irregular-shaped (Mg, Al)2Ca eutectic forms along grain boundary and its volume fraction gradually increases, meanwhile Mg2Ca and τ phase gradually decrease. The new fine lamellar Al4Sr appears when the Al content reaches to 7%. The additions of Sr and Ca improve the creep resistance of Mg-Al alloys significantly, and the Mg-5Al-2Sr-ICa and Mg-6Al-2Sr -1Ca alloys indicate the best creep properties in all studied alloys. According to the power-law equation, under conditions of 175℃/50~80 MPa and 70 MPa/150~200℃, the creep behavior of the Mg-4Al-2Sr alloy is diffusion controlled dislocation climb at lower stresses (〈 60 MPa) and shows the breakdown of power-law at higher stresses. The creep mechanism of the Mg-4Al-2Sr-1Ca alloy seems controlled dislocation movement and grain boundary sliding.

     

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