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半結晶性聚合物熔體冷卻過程雙尺度模擬

Double scale simulation of the cooling stage of semi-crystalline polymer melt

  • 摘要: 聚合物的結晶受溫度及溫度歷史影響較大,同時發生結晶又會對聚合物材料溫度場產生影響.為了準確模擬冷卻過程中溫度場和結晶情況,將半結晶性聚合物熔體冷卻過程及其結晶過程耦合起來分析,把宏觀溫度場結果作為介觀模擬的輸入,再把介觀模擬的球晶生長情況作為宏觀溫度場模擬的輸入,可同時得到宏觀與介觀二個尺度的模擬結果.由于該耦合建立在一定的物理基礎上,模擬得到的結果較為合理.

     

    Abstract: The crystallization behavior of a polymer is simultaneously influenced by temperature and temperature experience, but its temperature field is dependent on crystallization. A coupling analysis of cooling and crystallization process was carried out to exactly simulate the temperature field and crystallization behavior of se-mi-crystalline polymer melt. In the coupling method the result of temperature field was considered as the input of crystallization analysis and then the result of spherulites evolution was used as the input of temperature field simulation, so simulation results of the double scales, macroscopic and mesoscopic, was obtained at the same time. Because the coupling analysis has the physical background, the result of numerical simulation can be thought reasonable.

     

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