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在鈦合金表面制備Al-Si涂層的方法及其高溫抗氧化性

A way to fabricate an Al-Si coating on the surface of a Ti alloy and its high-temperature oxidation resistance

  • 摘要: 采用低氧壓高溫快速熔結技術在Ti-6Al-4V合金表面成功地制備出具有抗高溫氧化能力的Al-Si熔結涂層.與其他工藝相比,這種工藝相對簡單,且不需要經過長時間的加熱處理就能在合金的表面形成一層足夠厚度的Al-Si熔結涂層,不僅省時節能,且涂層中的抗氧化元素鋁、硅的濃度可通過調整涂層粉末的混合比例來進行控制.XRD檢測表明涂層主要由Al、Si、Ti5Si3和TiAl3相組成.在1073K空氣中循環氧化105h的實驗結果表明:未經過處理的鈦合金試樣的氧化增重一直保持著較高的增長速率;而對帶有低氧壓熔結Al-Si涂層的試樣來說,其氧化增重近似呈拋物線規律,顯著地提高了鈦合金的抗氧化能力.

     

    Abstract: An Al-Si fusing coating was successfully produced by low-oxygen pressure high-temperature fusing technology for improvement of the high-temperature oxidation resistance of Ti alloys. Compared with other technologies, this technology was correspondingly simple without long-term treatment and the concentrations of Al and Si in the fusing coating could be controlled by adjusting the powders' mixing ratio. It is verified by XRD that the Al-Si fusing coating is mainly composed of Al, Si, Ti5Si3, and TiAl3 phases. Cyclic oxidation tests at 1073 K for 105 h in air reveals that the mass gain of the uncoated Ti alloy keeps rapidly increasing during oxidation, while the Al-Si fusing coating obeys a parabolic law and remarkably improves the oxidation resistance.

     

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