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低碳鋼碳氮析出物的熱力學計算

Thermodynamic model for carbonitride precipitation in low carbon steels

  • 摘要: 鋼中的碳氮析出物通過細晶強化和析出強化方式對鋼的力學性能有非常重要的作用.基于規則溶液的雙亞點陣模型(其中一個為金屬亞點陣,另一個為間隙原子亞點陣)建立了碳氮化鈦、氮化鋁以及硫化錳的熱力學計算模型用以研究析出物的析出開始溫度、給定溫度的奧氏體成分,并將這一結果應用于CSP過程.經計算得Ti (CxN1-x),MnS和AlN的析出溫度分別是1200℃,1440℃和1010℃,最大的體積分數分別為2.315×10-5,4.18×10-4和3.1×10-4.對比發現熱力學的計算結果與Thermo-Calc的計算結果和有關文獻的實驗數據有較好的一致性.

     

    Abstract: Carbonitride precipitates have significant effects on the mechanical properties of steels via grain refinement and precipitation hardening. Based on the two-sublattice model (metal atom sublattice and interstitial atom sublattice) of regular solution, a thermodynamic model for the precipitates of titanium carbonitride, aluminium nitride and manganese sulfide was established to study the starting-temperature of precipitates and the austenite composition at a given temperature in a low carbon steel and applied to compact strip production (CSP for short) process. The calculation results show that starting-temperature of the precipitation of Ti(CxN1-x), MnS and AIN are 1200℃, 1 440℃ and 1 010℃, their mole fraction are 2.315×10-5, 4.18×10-4 and 3.1×10-4, respectively. By comparison the simulation results of the model are in agreement with the calculated ones by the Thermo-Calc software and the available experimental data from some publications. The thermodynamic model can be a useful tool in studying the precipitates of low carbon steels and in analyzing the CSP process.

     

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