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Zr和Nb摻雜對Nd2Fe14B/α-Fe納米復合永磁薄帶顯微組織和磁性能的影響

Effects of Zr and Nb dopants on the microstructure and magnetic properties of Nd2Fe14B/α-Fe nanocomposite ribbons

  • 摘要: 比較了Zr,Nb摻雜對Nd8·60Fe80·80Cu0·3Zr2-xNbxB8·30(x=0,1,2)交換耦合納米復合永磁薄帶相組成、顯微結構和磁性能的影響.結果表明:Zr和Nb均能有效地抑制晶粒的長大.Zr與B結合生成ZrB2,消耗了合金中部分B元素,導致合金中硬磁性相N2Fe14B含量的減少.與Zr相比,Nb能更有效地抑制晶粒長大,提高樣品磁滯回線的方形度.僅摻雜Nb的晶化樣品Nd8·60Fe80·80Cu0·3Nb2B8·30具有最佳的磁性能:Br=0·89T,Hci=479·1kA·m-1,(BH)max=107·4kJ·m-3.

     

    Abstract: ABSTRACT The effects of Zr and Nb dopants on the microstructure and magnetic properties of exchangecoupling nanocomposite Nd8.60Fe80.80Cu0.3Zr2-xNbxB8.30(x=0,1,2) ribbons were systematically studied. It is found that both Zr and Nb dopants can suppress the magnetic grain growth efficiently. The combination of Zr and B consumes partial B and induces to the reduction N2Fe14B phases. Comparing to the effect of Zr addition, Nb addition can improve the squareness of the hysteresis loop and suppress the magnetic grain growth more effectively. The optimum magnetic properties were found in the annealed Nd8.60Fe8 0.80Cu0.3Nb2B8.30 ribbons as the following: Br=0.89T,Hci=479.1kA·m-1,(BH)max=107.4kJ·m-3.

     

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