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長白山地區幔源捕虜體的硫化物相及其演化

Sulfide Phases and Their Evolution in Mantle Xenoliths from Changbaishan Mountain District in China

  • 摘要: 長白山地區新生代玄武巖的一些層位廣布地幔巖捕虜體,在其橄欖石、輝石等礦物內發現有較多的硫化物相,按產出特征可鑒別出3種類型,即早期硫化物顆粒、硫化物包裹體和裂隙中硫化物。硫化物包裹體可以單相硫化物、硫化物-硅酸鹽熔體、CO2-硫化物-硅酸鹽熔體形式存在。早期硫化物顆粒以磁黃鐵礦為主,并發現有方黃銅礦;硫化物包裹體以鎳黃鐵礦為主,并有黃銅礦、硫銅鐵礦出現;裂隙中硫化物均為鎳黃鐵礦,并具有比硫化物包裹體高的 Ni/Fe和(Fe+Ni)/S值。地幔巖中存在自早期硫化物顆粒、硫化物包裹體至裂隙硫化物,Ni/Fe和 (Fe+Ni)/S比值逐漸增加的規律。這種演化不僅受溫度和壓力制約,而且受Ni,Fe,Cu的地球化學特性和硫逸度的控制。

     

    Abstract: Mantle xenoliths occur widely in some strata of Cenozoic basalts in Changbaishan mountains, Jilin province. Sulfide phases are usually found in olivine and pyroxene of lherzolite, which can be identified into three typies:early sulfide grains, sulfide-melt inclusions and sulfides in fractures. Sulfide-melt inclusions occur as single-phase sulfide, sulfide-silicate melt, or CO2-sulfide-silicate melt inclusions. Early sulfide grains are mainly composed of pyrrhotite, but cubanite was found occasionally. Sulfide-melt inclusions are mainly composed of pentlandite, with small amounts of chalcopyrite and talnakhite. Sulfides in fractures are pentlandite without exception, which have higher Ni/Fe and (Fe+Ni)/S (molar ratio) than those of sulfide inclusions. Ni/Fe and (Fe+Ni)/S are gradually increased from early grains, sulfide inclusions to sulfides in fractures. These changes were not only controlled by temperatures and pressures, but by geochemistry of Ni, Fe and Cu, and sulfur fugacity as well.

     

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