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金川鎳閃速熔煉渣的物相與銅鎳分布

Microstructure and Metal Distribution in Jinchuan Nickel Smelting Slag

  • 摘要: 采用X射線衍射、光學顯微鏡、掃描電鏡和電子探針微區分析等方法,研究金川鎳閃速熔煉水淬渣的主要物相組成和有價金屬銅、鎳在爐渣中的存在形式.結果表明,水淬渣的主要結晶物相為鐵鎂橄欖石,結晶相之間由玻璃相填充,細小的銅鎳鐵硫化物以星散狀分布于爐渣中.有價金屬銅、鎳主要以硫化物形態存在于爐渣中,還有部分存在于鐵鎂橄欖石相中.

     

    Abstract: Phase composition of water quenched slap from the Jinchuan nickel flash smelting process and on the presence forms of copper and nickel in the slag is carried out using comprehensive modern analyse methods such as XRD, light microscope, SEM and EPMA. The results show that there are three main textures in the slag:(Fe,Mg)2SiO4-type crystalline Phase, glassy Phase and small(micrometer-size) sulphide droplets. Elements Cu and Ni are Present in the form of small droplets of mixed Cu,Ni,Fe-sulfides within the slag. Ni is also found as minor component of the crytalline(Fe,Mg)2SiO4-type Phase. Cu in not Present in the silicate part of the slag.

     

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