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SrTiO3中離子自擴散參數評估

Assessment of Diffusion Parameters in Strontium Titanate

  • 摘要: 評估了在未摻雜SrTiO3中氧的自擴散數據,得出:(1)在SrTiO3晶體中,氧通過氧空位擴散,擴散最快的離子為O2-,其次為Sr2-,最慢的為Ti4+.(2)在1098~1623 K范圍,氧分壓在0.2~7.6×104Pa內變化時,得到氧在SrTiO3晶體中的自擴散系數,而位錯密度和氧分壓對擴散系數影響不大.

     

    Abstract: The oxygen self-diffusion paramaters in strontium titanate were assessed. The results indicated that:(1) Oxygen diffusion occurs through a vacancy mechanism in strontium titanate crystals. The ranking of the ions based on the magnitude of diffusion coefficients is oxygen strontium and titanium ion. (2) In the temperature range from 1098 to 1623 K, under an oxygen partial pressure in the range from 0.2×104 to 7.6 ×104 Pa, the temperature dependence of the oxygen diffusion coefficient in strontium titanate is obtained. The diffusivity of the oxygen diffusion in strontium titanate is insensitive to the variation of oxygen panal pressure and the dislocation density.

     

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