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低溫Al2O3懸浮電解新工藝的研究

A New Process of Alumina Suspension Electrolysis

  • 摘要: 研究了利用低熔點氟氯化物體系作電解質的低溫Al2O3懸浮電解制鋁新工藝,從20~80A電解槽上進行的電解結果,推導了電流效率的計算表達式.結果表明,影響電流效率的主要因素是槽電流和產物鋁的表面積,增大槽電流和減小產物鋁的表面積都能使電流效率增大.在100A電解槽上實驗,當電解溫度為750℃,γ-Al2O3平均粒度為1.22μm,電解質中F-和Cl-的摩爾比為1時,電流效率達到86.3%,制取1kgAl的電耗為11.73kW·h.

     

    Abstract: A new process of low temperatUre Al2O3 suspension electrolysis for producing aluminum in low melting point fluo-chloride system was investigated. Current efficiency (η)expression deduced from experiments on 20~80A electrolysis cell showed that main effects on η are the cell current and the surface of aluminum produced.Increasing cell current and diminishing aluminum surface.can both make η increase. On an electrolysis cell of about 100A capacity with the fine γ-Al2O3 (media diam. 1.22μm) and the mixture in which F-/Cl- molar ratio was 1 at 750℃,aluminum metal was obtained with 86.3% current efficiency and 11.73 kW. h specific energy consumption.

     

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