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固態鉛、錫及其合金表面腐蝕動力學

Surface Corrosion Kinetics of the Solid Lead, Tin and Their Alloys

  • 摘要: 用增重法和俄歇能譜(AES)縱向濺射法,對冷軋Pb、Sn及其常量配比的Pb-Sn合金用3種不同腐蝕方法測定和計算了其腐蝕速度。實驗證明,Pb在實驗室大氣腐蝕、155℃干熱大氣腐蝕和100℃水蒸氣腐蝕下的腐蝕速度符合拋物線關系式。同時也證明,Sn和Pb-Sn合金在100℃水蒸氣下的腐蝕速度也符合拋物線關系式。并給出了155℃干熱腐蝕288h和大氣腐蝕2.5年的腐蝕層厚度數據。

     

    Abstract: The corrosion velocities of the cold-rolling strips of Pb, Sn and their alloys were investigated by the use of methods of the weight increase and AES longitudinal spattering. The parabolic relations of the corrosion velocity for the lead were obtained under the room temperature and atmosphere, of dryheating air 155℃ or water vapor at 100℃. Similar relations for Tin and Pb-Sn alloys were obtained in the atmosphere of watar vapour at 100℃. At the sametime the data on the thickness of the corrosion layers of the alloys and the metals in the dry-heating air at 155℃ for 288 h and in the atmosphere at the room temperature for two and a half years were also obtained.

     

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