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R1+εFe4B4化合物的超空間群對稱

The Superspace Group of R1+εFe4B4 Compounds

  • 摘要: 本文從Fe-B亞結構和R亞結構各自的對稱性出發,由超空間群理論對R1+εeB4化合物的結構對稱性進行了研究,結果表明,其對稱性可由PS1S1P4/nmm得到一般性的描述。

     

    Abstract: The crystal structures of R1+εFe4B4 compounds which were found in the permanent magnets R-Fc-B systems arc all built based on the two interpenetrating substructures. Fe-B substructure and R substructure, both have tetragonalsymmetry. Since the two substructures do not have the same periodicities in c direction, R1+εFe4B4 compounds form the so called Chimney-Ladder structureor Vernier structure which may belong to the incommensurate composite crystal structure. The translation symmetry of the incommensurate structure do not exist in three dimensional space and the superspace group theory has been developed for the description of the symmetry of incommensurate structure. In this paper, the superspace group theory is applied to the R1+εFe4B4 compounds. The result shows that the symmetry of R1+εFe4B4 compounds can be descripted by the general form PS1S1P4/nmm

     

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