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高硫鐵水變質處理新方法

Investigation of Modifying Treatment with Rare-Earth Oxide for High-sulphur Moltem

  • 摘要: 動用稀土氧化物固態渣餅作為脫硫劑和變質劑,借助吹氬攪拌對高硫(S=0.100%)過共晶鐵水進行變質處理。實驗在1450℃下進行30~45分鐘得到了變質處理過程中鐵水化學成分變化的規律和在過共晶鐵水條件下試樣中石墨形態和RE、CE含量之間的規律。
    結果表明在過共晶區當RE%≤(CE%-4.30%)/25時試樣石墨形態為蠕蟲狀。當RE%≥(CE%-4.30%)/25時試樣石墨形態為球狀。對脫硫反應和稀土氧化還原反應進行了熱力學計算和討論,在實驗條件下上述反應在熱力學上均成立。

     

    Abstract: Applying solid slag Cakes of rare earth oxide as a desulphurizinga gent as well as a modifying agent and under Condition of Ar-blowing, a hy-pereutictic hot metal of high Sulphur content (s=0.100%) has been mo-difyied. Experiments are made at 1450 ℃ for about 30~35 minutes.
    Changeing laws of chemical composition in hot metal and relationship between graphite morphogy and contentof RE, CE in casting are abta-ined. Results indicate that the RE% ≤ (CE%-4.30%)/25 and the RE% ≥ (CE%-4.30%)/25 canbe abtained vermicalar cast iror and nodular cast iron respectively under hypereutectic hot metal. with regrad to disuph-urizing reaction and redwction reaction of rare earth oxrde, discussion and thermodynamic calculation have been Carried out. The results point out that the above mentioned reaction are all established thermodyra-mically umder the experimental condition.

     

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