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氫對純鐵彈性模量的影響

Effect of Hydrogen on the Young’s Modulus of Iron

  • 摘要: 解出了應力作用下梁的橫向振動方程,結果表明,E=C(σ)ω2,E是揚氏模量,C是應力σ的函數,ω是樣品的固有頻率。同時測量基波和高次諧波的頻率,就可用計算機求出E和σ。
    用靜電激發調頻檢測法對比研究了電解充氫和人為部分應力松弛對純鐵揚氏模量的影響,結果表明:電解充氫能導致應力部分松弛,從而引起表觀彈性模量的下降;在充氫和人為部分應力松弛后的室溫時效過程中,應力都有部分回升,E也都升高0.1-0.3%;用排油取氣法測得室溫放出的氫量為7-8wppm,即7-8wppm的氫對和原子鍵合力有關彈性模量沒有明顯影響。
    也應用懸絲共振法研究了氫對純鐵彈性模量的影響并獲得了同樣的結果。

     

    Abstract: The flexural vibration equation of a beam under stress is set up. The solution of the equation indicates E=C (α)ω2, where E stands for the apparent Young's modulus, C for a function of stress, and ω for the intrinsic frequency of sample. If the resonant frequencies of the first tone and the third one are measured at about same time, E and σ can be calculated.
    The change of the apparent Young's modulus after charging with hydrogen is difined as ΔE=ΔE1 (H) + ΔE2, where ΔE1 (H) has relation with the change of the perfect crystal interatomic cohesive force and ΔE2 is induced by the change of stress. An artificially partial stress relaxation test was done to measure ΔE2. The results show that during ageing after both charging with hydrogen and artificial stress releasing, the apparent modulus increased by 0.1-0.3%, i.e 0ΔE=ΔE2. Thus, the ΔE1 (H) associated with the interatomic cohesive force does not evidently change during the ageing with evolving hydrogen of 7-8 wppm, i.e. hydrogen of 7-8 wppm does not significantly decrease the interatomic cohesive force of α-Fe.
    The Forster's horizontal free-free bar apparatus was also used to measure the change of Young's modulus of a-Fe caused by hydrogen. The same conclusion was obtained.

     

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