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GH36合金中的VCM23C6和高溫持久缺口敏感性

Precipitates of VC M23C6 and Stress Rupture Notch Sensitivity of Superalloy GH36

  • 摘要: 使用薄膜TEM直接觀察了成分相近熱處理制度不同的兩個爐號GH36合金的基本組織,使用SAD和DF技術做物相分析。結果表明,合金經正常熱處理后析出細小彌散分布的VC,尺寸約在2nm~12nm,還有M23C6和N6C、其中VC和M23C6與合金基體的取向關系是011vc∥011M∥011M23C6,(111)VC∥(111)M∥(111)M23C6,(200)VC∥(200)M∥(200)M23C6,通過補充時效后合金中VC顆粒聚集長大,晶界析出的M23C6更多,這種組織及晶界狀態有利于改善合金的持久缺口敏感性。

     

    Abstract: The structure analyses of two GH36 superalloy turbine disks with different heat treatments were conducted by thin foil TEM. The preci-tates in GH36 super alloy were identified as VG, M23C6 and NbC by SAD. Electron diffraction patterns show the orintation relationship between precipitates and matrix as following:\\beginarrayl\rm011_\rmvc\rm||011\rm_\rmM\rm||011\rm_\rmM_\rm23\rmC_\rm6\\\rm111_\rmvc\rm||111\rm_\rmM\rm||111\rm_\rmM_\rm23\rmC_\rm6\\\rm200_\rmvc\rm||200\rm_\rmM\rm||200\rm_\rmM_\rm23\rmC_\rm6\endarray\Moire patterns and dark field show that the size of VC precipitates after normal heat treatment varies from 3 to 12nm. The size of VC after superimposed higher temperature aging grows in a few nm larger and more M23C6 carbide precipitates in alloy than norma heat treatment. Thus, the yield stress and stress rupture strength decrease, but the stress rupture notch sensitivity has been improved.

     

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