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12SiMoVNb抗氫鋼碳化物與抗氫腐蝕關系

The Relation of Hydrogen Attack and Alloy Carbides in steel 12SiMoV Nb Steel

  • 摘要: 抗氫鋼中形成穩定的合金碳化物以固定碳,避免在高溫、高壓下與氫作用形成甲烷造成氫損傷,這不僅與鋼材成分的合理設計有關,而且與合理選擇熱處理制度密切有關。本文采用綜合相分析方法對12SiMoVNb合金碳化物析出及其與氫相互作用行為進行探討,指出采用~1000℃正火及720℃~740℃高溫回火,以獲得在鐵素體基體上分布著以V4C3為主的彌散碳化物,以及Mo、V、Nb元素固溶強化是該合金獲得綜合力學性能,特別是高溫(400℃PH2=200kg/cm2)抗氫腐蝕性能的關健。

     

    Abstract: In the hydrogen resistant steel alloy carbides are formed to fix carbon so as to avoid the formation of methane at Fe3C, that causes hydrogen damage.This Process depends not only on an appropriate design of the steel composition, but also on aproper selection of heat treatment This research was doneby using complex phase analysis method to study the precipitation of alloy carbides and their relationship with hydrogen in 12SiMoVNb steel.
    By normanizatibn at lOOO℃ and tempering at 720-740tJ small carbides (most one of them is V4C3) distribute in the ferrite matrix and solid solution strengthening by Mo% V, Nb were obtained. They are both decisive factors in achieveing good arc mechanical properties and promoting the resistance against hydrogen attack at 400t and at PH2-200 kg/cm2.

     

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